Igama: | Ethyl 4-bromobutyrate |
Isithethantonye: | I-4-Bromobutanoic acid, i-ethyl ester;I-BRCH2CH2CH2C(O)OC2H5; I-asidi ye-butanoic, i-4-bromo-, i-ethyl ester;I-Ethyl 4-bromobutanoate; I-Ethyl gamma-bromobutyrate;I-ETHYL 4-BROMO-N-BUTYRATE; ETHYL GAMMA-BROMO-N-BUTYRATE |
I-CAS: | 2969-81-5 |
Ifomula: | C6H11BrO2 |
Imbonakalo: | Ulwelo olutyheli kancinane |
EINECS: | 221-005-6 |
Ikhowudi yeHS: | 2915900090 |
Kwibhotile yokusabela ene-stirrer, i-thermometer kunye ne-vent tube, i-200 g (2.33 mol) ye-γ -butyrolactone kunye ne-375mL ye-ethanol ye-anhydrous yongezwa, ipholile ukuya kwi-0 ℃ kwindawo yokuhlambela ityuwa ye-ice, kunye negesi eyomileyo ye-hydrogen bromide yaziswa de. i-reactants yahlala ingatshintshi, eyathatha malunga neeyure ze-2.Yiyeke ngo 0℃ kangange 24h.Thela i-reactant kwi-1L yamanzi abandayo, ugxobhoze ngokupheleleyo, uhlukanise i-organic layer, kwaye ukhuphe umaleko wamanzi nge-bromoethane kabini, i-10mL ngexesha ngalinye.Ukudibanisa i-organic layers, ukuhlamba i-ethanol kunye ne-2% yesisombululo se-potassium hydroxide, i-dilute hydrochloric acid kunye namanzi, ukomisa nge-anhydrous sodium sulfate, ukubuyisela i-solvent, i-vacuum fractionation, kunye nokuqokelela amaqhezu kwi-97 ~ 99℃/3.3 kPa ukufumana i-350 ~ 380 g ye-ethyl γ-bromobutyrate (1) kunye nesivuno se-77% ~ 84%.
I-Ethyl 4- bromobutyrate yi-carboxylate derivative, engenambala, ebonakalayo kulwelo olutyheli.Ingasetyenziswa njengendawo ephakathi yezibulali zinambuzane kunye namayeza, kwaye ingasetyenziselwa uphando lwebhubhoratri kunye nophuhliso kunye nokuveliswa kweekhemikhali.
IBanga lokuPakisha: I;II
ICandelo loMngcipheko: 6.1
Ikhowudi yeHS: 2915900090
WGK_Germany (Uludwe loHlelo lweMithombo yoNgcoliseko lwaManzi eJamani): 3
IKhowudi yoHlelo lweeNgozi: R22;R36/37/38
Imiyalelo yoKhuseleko: S26-S36-S37/39
Uphawu lokhuseleko: S26: Xa udibana namehlo, hlambulula ngokukhawuleza ngamanzi amaninzi kwaye uthumele kugqirha.
S36: Nxiba iimpahla ezifanelekileyo ezikhuselayo.
Iimpawu zeNgozi: Xn: Ziyingozi